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Answer by Devgeet Patel for Why Cl⁻ can't act as bidentate ligand?

Chlorine ion is monodentate.For bidentate ligand it should have atleast two bonding sites.In chlorine it has only one donatable lone pair.So it can't act as bidentate ligand.

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Answer by Ben Norris for Why Cl⁻ can't act as bidentate ligand?

A bidentate ligand is one that forms bonds to the metal center through two different atoms, not through two lone pairs. While chloride does have more than one pair of valence electrons, it only has one...

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Why Cl⁻ can't act as bidentate ligand?

$\ce{Cl-}$ is a monodentate ligand. It has four lone pairs then why it can't donate two lone pairs to central atom and act as a bidentate ligand?

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